Monovalent Copper Ligands (MCL-Series)
Thermodynamic Data
Ligand | E (V vs. SHE) | pKa | logKCu(II)L | logKCu(I)L | logK'Cu(I)L | pCu |
MCL-1 | 0.716(1) | 7.00(2) | 6.42(2) | 16.33(2) | 16.0 | 16.9 |
MCL-2 | n/a | 8.98(1) | - | 13.08(13) | 11.0 | 11.9 |
MCL-3 | 0.729(3) | n/a | 3.47(4) | 13.80(3) | 13.8 | 14.8 |
Calculate the Apparent Affinity (I = 0.1)
Structures of Cu(I) Complexes
MCL-1   (cif file) |
MCL-2   (cif file) |
trMCL-3   (cif file) |